Remarkable effects of P-perfluorophenyl group on the synthesis of core-modified phosphaporphyrinoids and phosphadithiasapphyrin.
Remarkable effects of P-perfluorophenyl group on the synthesis of core-modified phosphaporphyrinoids and phosphadithiasapphyrin.
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DOI：
10.1021/ol100114j
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发表时间：
2010-02
期刊：
影响因子：
5.2
通讯作者：
Takashi Nakabuchi;Y. Matano;H. Imahori
中科院分区：
文献类型：
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作者：
Takashi Nakabuchi;Y. Matano;H. Imahori
以1-全氟苯基-2,5-二（乙氧羰基）磷孔为原料，以高总收率制备了核心磷原子为全氟苯基(C（6)F(5)）基团的P、X、N(2)型磷卟啉和磷酰基卟啉（X = N， S）。此外，成功制备了P- c (6)F(5) P，S(2)，N(2)型卟啉，这是第一个扩环含磷卟啉的例子。
P,X,N(2)-type phosphaporphyrins and phosphacalixphyrins (X = N, S) bearing a perfluorophenyl (C(6)F(5)) group at the core phosphorus atom were prepared in high overall yield from 1-perfluorophenyl-2,5-di(ethoxycarbonyl)phosphole as a common starting material. In addition, P-C(6)F(5) P,S(2),N(2)-type sapphyrin was successfully prepared as the first example of ring-expanded phosphorus-containing porphyrin.