Crystal Structure and Optical Properties of (CH3)2NH2CuCl3

Crystal Structure and Optical Properties of (CH3)2NH2CuCl3
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(CH3)2NH2CuCl3 的晶体结构和光学性质

DOI:
10.1063/1.1726475
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发表时间:
1966
期刊:
影响因子:
--
通讯作者:
R. Willett
R. Willett
中科院分区:
--
文献类型:
--
作者:
R. Willett

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(CH3)2NH2CuCl3 的晶体结构已通过 X 射线衍射技术确定。该化合物含有近似平面的 Cu2Cl6= 二聚体,其中含有两个桥连氯原子。二聚体中的所有 Cu-Cl 键距约为 2.3 A,所有键角约为 90°。当电矢量平行于[301]方向时,晶体具有最大可见光吸收的多向色性。
The crystal structure of (CH3)2NH2CuCl3 has been determined by x‐ray diffraction techniques. The compound contains approximately planar Cu2Cl6= dimers which contain two bridging chlorine atoms. All Cu–Cl bond distances in the dimer are approximately 2.3 A and all bond angles approximately 90°. The crystals are pleochroic with maximum visible absorption when the electric vector is parallel to the [301] direction.