High sulfur content polymers: The effect of crosslinker structure on inverse vulcanization

High sulfur content polymers: The effect of crosslinker structure on inverse vulcanization
复制标题

高硫含量聚合物:交联剂结构对逆硫化的影响

DOI:
--
复制
发表时间:
2018
期刊:
Journal of Polymer Science Part A: Polymer Chemistry
影响因子:
--
通讯作者:
T. Hasell
T. Hasell
中科院分区:
--
文献类型:
--
作者:
Jessica A. Smith;Xiaofeng Wu;N. Berry;T. Hasell

文献摘要

参考文献

被引文献

相似文献

反硫化的发现使得聚合物可以使用元素硫作为主要组分来制备。然而,到目前为止,很少有人讨论为什么看似相似的交联剂会导致聚合物具有根本不同的性能。结合合成,光谱学和建模,这项研究揭示了硫聚合物的结构-性能关系,并报告了一种使用5-亚乙基-2-丁烯作为交联剂的新系统,可以稳定高达90重量%的元素硫。
The discovery of inverse vulcanization has allowed polymers to be made using elemental sulfur as the major component. However, until now, there has been little discussion of why seemingly similar crosslinkers result in polymers with radically different properties. Combining synthesis, spectroscopy, and modeling, this study reveals the structure–property relationships of sulfur polymers and reports a new system using 5‐ethylidene‐2‐norbornene as a crosslinker that can stabilize up to 90 wt % of elemental sulfur.
DOI: 10.1039/c6ta09862b
发表时间: 2017-06-21
影响因子: 11.9
作者:
Parker, D. J.;Jones, H. A.;Hasell, T.
通讯作者: Hasell, T.