Preparation of siloxacyclopentene containing 1,3-dienes and their Diels-Alder reactions

Preparation of siloxacyclopentene containing 1,3-dienes and their Diels-Alder reactions
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DOI:
10.1016/j.tetlet.2007.08.133
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发表时间:
2007-10-29
影响因子:
1.8
通讯作者:
Welker, Mark E.
Welker, Mark E.
中科院分区:
化学4区
文献类型:
--
作者:
Pidaparthi, Ramakrishna R.;Welker, Mark E.

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制备了一系列的乙烯氧基二甲基硅烷和二异丙基硅烷,并通过炔烃官能团的分子内硅氢化反应转化为含1,3-二烯的硅氧基环戊烯。报道了这些二烯的Diels-Alder反应。(C) 2007 Elsevier Ltd.版权所有。
A number of enynyloxy dimethyl and diisopropyl silanes have been prepared and converted into siloxacyclopentene containing 1,3-dienes via intramolecular hydrosilylation of the alkyne functional group. Diels-Alder reactions of these dienes are reported. (C) 2007 Elsevier Ltd. All rights reserved.