Electrochemical Fabrication and Characterization of Silicon Microwire Anodes for Li Ion Batteries
Electrochemical Fabrication and Characterization of Silicon Microwire Anodes for Li Ion Batteries
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DOI：
10.1149/2.0111603jes
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发表时间：
2016
影响因子：
3.9
通讯作者：
Sandra Nöhren;E. Quiroga‐González;J. Carstensen;H. Föll
中科院分区：
文献类型：
--
作者：
Sandra Nöhren;E. Quiroga‐González;J. Carstensen;H. Föll
利用基于电化学蚀刻的允许大规模生产的技术，生产用于锂离子电池阳极的硅微丝阳极。该线由于其直径在微米范围内而表现出高的面容量，并且由于在它们中的每一个周围形成均匀的固体电解质界面而表现出高的循环稳定性。这项研究总结了（准确的）电池工作参数的重要性和它们对导线尺寸的依赖性。此外，它比较了两个阳极的概念，其中的电线可以被纳入。FFT阻抗分析显示了特定条件下的特性电阻变化，这些特性电阻直接与操作期间导线中的过程相关，有助于其优化。版权所有作者2015.由ECS发布。这是一篇开放获取的文章，根据知识共享署名4.0许可证（CC BY，http：//creativecommons.org/licenses/by/4.0/）的条款分发，该许可证允许在任何媒体上不受限制地重复使用作品，前提是正确引用原始作品。[DOI：10.1149/2.0111603jes]版权所有。
With a technique allowing for large-scale production, which is based on electrochemical etching, silicon microwire anodes for Li ion batteries anodes are produced. The wires exhibit high areal capacity due to their diameters in the micron-range, and high cycling stability due to the formation of a homogeneous solid electrolyte interface around each of them. This study summarizes the importance of the (exact) battery work parameters and their dependence on the wire dimensions. Furthermore, it compares two anode concepts in which the wires can be incorporated. FFT-impedance analysis shows the characteristic resistance changes under specific conditions, which relate directly to the processes in the wires during operation, what helps for their optimization. © The Author(s) 2015. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY, http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium, provided the original work is properly cited. [DOI: 10.1149/2.0111603jes] All rights reserved.