Chemically transformed monolayers on acene thin films for improved metal/organic interfaces
Chemically transformed monolayers on acene thin films for improved metal/organic interfaces
复制标题
并苯薄膜上的化学转化单分子层可改善金属/有机界面
DOI：
10.1039/c9cc07234a
复制
发表时间：
2019
影响因子：
4.9
通讯作者：
Ciszek, Jacob W.
中科院分区：
文献类型：
--
作者：
Li, Feifei;Hopwood, Jonathan P.;Galey, Melissa M.;Sanchez, Laura M.;Ciszek, Jacob W.
酸酐封端的并苯薄膜被化学转化为硫醇或羧酸官能团，迄今为止与单层反应不相容的基团。当形成酰亚胺时，分子表面赋予大的速率加速，而不利的二硫化物可以由硫醇形成。改性的表面在柔性/可弯曲应用中赋予对顶部金属触点的改进的粘附性。
Anhydride terminated acene thin films were chemically transformed to thiol or carboxylic acid functionalities, groups heretofore incompatible with monolayer reactions. The molecular surface imparts large rate acceleration when imides are formed, while disfavored disulfides can be formed from the thiols. The modified surface imparts improved adhesion to top metal contacts in flexible/bendable applications.