Type 3 porous liquids based on non-ionic liquid phases - a broad and tailorable platform of selective, fluid gas sorbents.
Type 3 porous liquids based on non-ionic liquid phases - a broad and tailorable platform of selective, fluid gas sorbents.
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基于非离子液体相的3型多孔液体 - 选择性，流体气体吸附剂的宽阔且可定制的平台。
DOI：
10.1039/c9sc05770f
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发表时间：
2020-01-09
期刊：
影响因子：
8.4
通讯作者：
James SL
中科院分区：
文献类型：
--
作者：
Cahir J;Tsang MY;Lai B;Hughes D;Alam MA;Jacquemin J;Rooney D;James SL
我们描述了一系列的3型多孔液体，表示为“T3PLs”，基于广泛的微孔固体，包括MOF，沸石和多孔性有机聚合物(PAF-1)。这些固体分散在各种非离子液体相中(包括硅油、甘油三酯油和聚乙二醇)，这些非离子液体具有一系列的结构和性质，并且在许多情况下是立体地从固体的孔隙中排除的。得到了几种稳定的高吸气率的分散体。我们展示了如何针对重要的气体分离过程(CO2/CH4、C2H4/C2H6)和需要生物兼容性的应用定制这些分散体。我们描述了一系列的3型多孔液体，表示为“T3PLs”，基于广泛的微孔固体，包括MOF，沸石和多孔性有机聚合物(PAF-1)。
We describe a series of Type 3 porous liquids, denoted “T3PLs”, based on a wide range of microporous solids including MOFs, zeolites and a porous organic polymer (PAF-1). These solids are dispersed in various non-ionic liquid phases (including silicone oils, triglyceride oils, and polyethylene glycols) which have a range of structures and properties, and that are in many cases sterically excluded from the pores of the solids. Several stable dispersions with high gas uptakes are obtained. We show how these dispersions can be tailored toward important gas separation processes (CO2/CH4, C2H4/C2H6) and applications that require biocompatibility. We describe a series of Type 3 porous liquids, denoted “T3PLs”, based on a wide range of microporous solids including MOFs, zeolites and a porous organic polymer (PAF-1).
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影响因子：
16.6
作者：
Liu, Huang;Liu, Bei;Lin, Li-Chiang;Chen, Guangjin;Wu, Yuqing;Wang, Jin;Gao, Xueteng;Lv, Yining;Pan, Yong;Zhang, Xiaoxin;Zhang, Xianren;Yang, Lanying;Sun, Changyu;Smit, Berend;Wang, Wenchuan
通讯作者：
Wang, Wenchuan
影响因子：
64.8
作者：
Giri, Nicola;Del Popolo, Mario G.;James, Stuart L.
通讯作者：
James, Stuart L.
影响因子：
3.9
作者：
Liu, Shengjun;Liu, Jiandang;Liu, Bo
通讯作者：
Liu, Bo
影响因子：
15
作者：
Aguado, Sonia;Bergeret, Gerard;Farrusseng, David
通讯作者：
Farrusseng, David
影响因子：
4.9
作者：
Hartlieb, Karel J.;Ferris, Daniel P.;Stoddart, J. Fraser
通讯作者：
Stoddart, J. Fraser