Explosive Boiling of Superheated Cryogenic Liquids
Explosive Boiling of Superheated Cryogenic Liquids
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DOI：
10.1002/9783527610662
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发表时间：
2007-04
期刊：
影响因子：
--
通讯作者：
V. Baidakov
中科院分区：
文献类型：
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作者：
V. Baidakov
前言。前言。1绪论。2均衡性、稳定性和亚稳性。2.1平衡类型：稳定性准则。2.2本质不稳定的边界。2.3统计理论的要素。2.4抗有限扰动的相位稳定性。2.5临界异相波动。2.6亚稳定相的弛豫过程。2.7异相波动的动力学。2.8动力学成核理论(多参数版)。2.9经典成核理论的近似性和局限性。2.10亚稳程度较高的形核。2.11绕过鞍点成核。2.12关于成核理论的几点评论。3可实现单组分液体的过热。3.1确定临界气泡形成功的两种方法。3.2过热液体的沸腾动力学。3.3成核随机理论的要素。3.4过热液体沸腾分析的实验程序。3.5研究液体极限过热度的准静态方法。3.6研究液体爆炸沸腾的动态方法。3.7关于经典液体的实验结果。3.8量子液体的过热。3.9汽核的表面张力。3.10低温液体的空化强度。3.11液态Ar在负压下可达到的过热。3.12开始形核。3.13异质形核。4液化气溶液中的成核作用。4.1临界核及其形成工作。4.2二元溶液中的成核理论。4.3碳氢化合物溶液的可达到过热。4.4低温液体溶液的实验方法。4.5具有组件完全溶解能力的解决方案。4.6各组分具有部分溶解度的溶液。4.7溶液热力学稳定性的状态方程和边界。4.8二元溶液中临界气泡的性质。4.9二元溶液的理论和实验的比较。4.10三组分溶液成核的动力学和热力学。4.11低温液体三元溶液的可达过热度。5高关联系统中的成核作用。5.1引言。5.2关键配置及其稳定性。5.3稳态成核。5.4临界区新相形成的特点。5.5临界点和三临界点附近成核的实验研究。5.6理论与实验的比较。5.7在调幅曲线附近的形核。5.8调幅分解理论。5.9调幅分解的实验研究。6绝对零度附近的形核动力学。6.1原子核的量子隧道效应。6.2 4He-3He溶液的极限过饱和度。6.3超流氦中量子涡的形成。6.4本质不稳定边界附近的量子成核。6.5氦中的量子空化。6.6关于相亚稳性的其他一些问题。7低温液体的爆炸沸腾。7.1流出过程中的过热。7.2两种不同液体界面上的蒸汽爆炸。符号列表。参考资料。索引。
Foreword. Preface. 1 Introduction. 2 Equilibrium, Stability, and Metastability. 2.1 Types of Equilibria: Stability Criteria. 2.2 Boundary of Essential Instability. 2.3 Elements of Statistical Theory. 2.4 Phase Stability Against Finite Perturbations. 2.5 Critical Heterophase Fluctuations. 2.6 Relaxation Processes in Metastable Phases. 2.7 Dynamics of Heterophase Fluctuations. 2.8 Kinetic Nucleation Theory (Multiparameter Version). 2.9 Approximations and Limitations of Classical Nucleation Theory. 2.10 Nucleation at a High Degree of Metastability. 2.11 Nucleation Bypassing the Saddle Point. 2.12 Some Comments on Nucleation Theory. 3 Attainable Superheating of One-Component Liquids. 3.1 Two Approaches to the Determination of theWork of Formation of a Critical Bubble. 3.2 Boiling-Up Kinetics of Superheated Liquids. 3.3 Elements of the Stochastic Theory of Nucleation. 3.4 Experimental Procedures in the Analysis of Boiling in Superheated Liquids. 3.5 Quasistatic Methods of Investigating Limiting Superheatings of Liquids. 3.6 Dynamic Methods of Investigating Explosive Boiling-Up of Liquids. 3.7 Results of Experiments on Classical Liquids. 3.8 Superheating of Quantum Liquids. 3.9 Surface Tension of Vapor Nuclei. 3.10 Cavitation Strength of Cryogenic Liquids. 3.11 Attainable Superheating of Liquid Argon at Negative Pressures. 3.12 Initiated Nucleation. 3.13 Heterogeneous Nucleation. 4 Nucleation in Solutions of Liquefied Gases. 4.1 Critical Nucleus and the Work of its Formation. 4.2 Theory of Nucleation in Binary Solutions. 4.3 Attainable Superheating of Solutions of Hydrocarbons. 4.4 Methods of Experimentation on Solutions of Cryogenic Liquids. 4.5 Solutions with Complete Solubility of the Components. 4.6 Solutions with Partial Solubility of the Components. 4.7 Equation of State and Boundaries of Thermodynamic Stability of Solutions. 4.8 Properties of Critical Bubbles in Binary Solutions. 4.9 Comparison of Theory and Experiment for Binary Solutions. 4.10 Kinetics and Thermodynamics of Nucleation in Three-Component Solutions. 4.11 Attainable Superheatings of Ternary Solutions of Cryogenic Liquids. 5 Nucleation in Highly Correlated Systems. 5.1 Introduction. 5.2 Critical Configuration and its Stability. 5.3 Steady-State Nucleation. 5.4 Peculiarities of New Phase Formation in the Critical Region. 5.5 Experimental Investigations of Nucleation in the Vicinity of Critical and Tricritical Points. 5.6 Comparison of Theory and Experiment. 5.7 Nucleation in the Vicinity of a Spinodal Curve. 5.8 Theory of Spinodal Decomposition. 5.9 Experimental Studies of Spinodal Decomposition. 6 Nucleation Kinetics Near the Absolute Zero of Temperature. 6.1 Quantum Tunneling of Nuclei. 6.2 Limiting Supersaturations of 4He-3He-Solutions. 6.3 Formation of Quantum Vortices in Superfluid Helium. 6.4 Quantum Nucleation Near the Boundary of Essential Instability. 6.5 Quantum Cavitation in Helium. 6.6 Some Other Problems of Phase Metastability. 7 Explosive Boiling-Up of Cryogenic Liquids. 7.1 Superheating in Outflow Processes. 7.2 Vapor Explosion at the Interface of Two Different Liquids. List of Symbols. References. Index.