On the nature of dendrimer cross-linking by ring-closing metathesis
On the nature of dendrimer cross-linking by ring-closing metathesis
复制标题
DOI：
10.1021/ja045885j
复制
发表时间：
2004-10-27
影响因子：
15
通讯作者：
Zimmerman, SC
中科院分区：
文献类型：
--
作者：
Beil, JB;Lemcoff, NG;Zimmerman, SC
研究了树枝状大分子1及其亚基的闭环复分解（RCM）介导的交联。通过MALDI-MS-TOF、SEC、NMR和X-射线晶体学分析的组合使用，表明交联按以下优先顺序形成：类型≥类型c>类型b>类型a。
The ring-closing metathesis (RCM) mediated cross-linking of dendrimer1and it subunits was examined. Through the combined use of MALDI-MS-TOF, SEC, NMR, and X-ray crystallographic analysis it was shown that the cross-links are formed with the following order of preference: typed≥ typec> typeb≫ typea.