Syntheses and magnetic properties of high-dimensional cucurbit[6]uril-based metal-organic rotaxane frameworks
Syntheses and magnetic properties of high-dimensional cucurbit[6]uril-based metal-organic rotaxane frameworks
复制标题
高维葫芦[6]脲基金属有机轮烷骨架的合成及磁性能
DOI：
10.1039/c9dt01544b
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发表时间：
2019
影响因子：
4
通讯作者：
Su Zhong-Min
中科院分区：
文献类型：
--
作者：
Wu Xue-Song;Bao Hong-Fei;Zhu Fu-Long;Sun Jing;Wang Xin-Long;Su Zhong-Min
通过水热合成方法获得了三种新型高维葫芦[6]基金属有机轮烷骨架[Co2(PR43)(BDC)2Cl2]·4H2O (1)、[Co2(PR43)(BTC)2]·6H2O (2)和[Co2(PR43)(BPT)2]·20H2O (3)。化合物1具有二维层状结构，而化合物2和3则呈现三维柱状结构。所有化合物均表现出良好的热稳定性。此外，还详细研究了化合物1-3的磁性。
Three new high-dimensional cucurbit[6]-based metal–organic rotaxane frameworks [Co2(PR43)(BDC)2Cl2]·4H2O (1), [Co2(PR43)(BTC)2]·6H2O (2) and [Co2(PR43)(BPT)2]·20H2O (3) were obtained via the hydrothermal synthesis method. Compound 1 comprised a two-dimensional layered structure, while compounds 2 and 3 exhibited three-dimensional pillared structures. All the compounds showed good thermal stabilities. Furthermore, the magnetic properties of compounds 1–3 were also investigated in detail.