Design of latent catalysts and their application to polymer synthesis
Design of latent catalysts and their application to polymer synthesis
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DOI：
10.1002/masy.19961070123
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发表时间：
1996-04-01
影响因子：
--
通讯作者：
Sanda, F
中科院分区：
文献类型：
--
作者：
Endo, T;Sanda, F
介绍了苄基锍盐、苄基铵盐、苄基吡啶盐、苄基鏻盐和肼盐等潜催化剂的设计及其在高分子合成中的应用。它们已被证明是用于环状单体如环氧化物、双环原酸酯、螺环原碳酸酯和乙烯基单体如苯乙烯和乙烯基醚的聚合的优异的热或光潜催化剂。
Design of latent catalysts such as benzyl sulfonium, benzyl ammonium, benzyl pyridinium, benzyl phosphonium, and hydrazinium salts, and their application to polymer synthesis have been described. They have been demonstrated as excellent thermal or photolatent catalysts for polymerizations of cyclic monomers such as epoxides, bicycle orthoesters, spiro orthocarbonates, and vinyl monomers such as styrene and vinyl ethers.