Catalytic intermolecular allyl-allyl cross-couplings between alcohols and boronates
Catalytic intermolecular allyl-allyl cross-couplings between alcohols and boronates
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DOI：
10.1039/c1cc13348a
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发表时间：
2011-01-01
影响因子：
4.9
通讯作者：
Kobayashi, Shu
中科院分区：
文献类型：
--
作者：
Jimenez-Aquino, Agustin;Flegeau, Emmanuel Ferrer;Kobayashi, Shu
我们开发了各种烯丙醇和烯丙基硼酸酯之间的催化分子间C（sp（3））-C（sp（3））交叉偶联，其在镍（0）的存在下在温和条件下顺利进行以形成具有优异的线性和γ-选择性的1，5-二烯;硼酸酯的使用被证明在反应性方面是至关重要的。
We developed catalytic intermolecular C(sp(3))-C(sp(3)) cross-couplings between various allyl alcohols and allyl boronates, which proceeded smoothly in the presence of nickel(0) under mild conditions to form 1,5-dienes with excellent linear- and gamma-selectivity; the use of boronates proved to be crucial in terms of reactivity.