New simple functions to describe kinetic and thermodynamic effects of pressure. Application to Z−E isomerization of 4-(dimethylamino)-4'-nitroazobenzene and other reactions
New simple functions to describe kinetic and thermodynamic effects of pressure. Application to Z−E isomerization of 4-(dimethylamino)-4'-nitroazobenzene and other reactions
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描述压力的动力学和热力学效应的新简单函数在 4-(二甲氨基)-4-硝基偶氮苯的 Z−E 异构化和其他反应中的应用。
DOI：
10.1021/j150646a015
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发表时间：
1984
期刊：
影响因子：
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通讯作者：
T. Okada
中科院分区：
文献类型：
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作者：
T. Asano;T. Okada
结论Meyerand Dietz（14·15）的各向异性吸附势模型应用于分子吸附理论时，能较好地预测烷烃和芳香烃在石墨上的吸附热力学函数，至少与经验吸附势规律吻合。考虑到石墨的高各向异性极化率的吸附势可以用Lennard-Jones（12-6）势很好地近似表示。用于计算石墨各向同性吸附势的kirkwood - m<s:1> ller常数比假设基底平面垂直方向的极化率为零的吸引常数大4/3。因此，吸附势定律
ConclusionThese results show that the anisotropic adsorption potential model of Meyerand Dietz, 14· 15 when applied to the molecular theory of adsorption, predicts with good agreement, at least as well as the empirical adsorption potential laws, the thermodynamic functions of adsorption of alkanes and aromatic hydrocarbons on graphite.The adsorption potential which takes into account the high anisotropic polarizability of graphite can be expressed with a good approximation by a Lennard-Jones (12-6) potential. The Kirkwood-Müller constant used for isotropicadsorption potential calculations on graphite is 4/3 larger than the attractive constant which assumes that the polarizability in the direction normal to the basal plane is zero. Therefore, adsorption potential laws which