Ammonia borane destabilized by aluminium hydride: A mutual enhancement for hydrogen release
Ammonia borane destabilized by aluminium hydride: A mutual enhancement for hydrogen release
复制标题
氨硼烷被氢化铝破坏稳定：氢释放的相互增强
DOI：
10.1016/j.ijhydene.2014.11.065
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发表时间：
2015-01
影响因子：
7.2
通讯作者：
Yu Xuebin
中科院分区：
文献类型：
--
作者：
Wan Lei;Chen Jie;Tan Yingbin;Yu Xuebin
Destabilized by aluminum hydride, the dehydrogenation properties of ammonia borane (AB) can be improved significantly, including enhanced dehydrogenation kinetics, reduced induction period and suppressed formation of volatile byproducts. Furthermore, a lowered dehydrogenation temperature was also achieved for AlH3, indicating a mutual dehydrogenation enhancement for both AB and AlH3in this mixture. The destabilized sample, 3AB/AlH3,can totally release more than 12 wt% of high-pure hydrogen (>99 wt%) without any detectable by-products below 250 °C. Mechanism investigations indicated that the mutual dehydrogenation enhancement in the mixture is attributed to the Coulombic attraction between the hydridic Hδ−in AlH3and the protonic Hδ+in the NH3group of AB.
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影响因子：
--
作者：
Yaoqi Li;Ping Song;Jie Zheng;Xingguo Li
通讯作者：
Yaoqi Li;Ping Song;Jie Zheng;Xingguo Li
用现成的镁粉进行机械研磨以促进氨硼烷中的氢释放
影响因子：
3.7
作者：
Wang, Ping;Luo, Jun-Hong;Kang, Xiang-Dong
通讯作者：
Kang, Xiang-Dong
影响因子：
2.9
作者：
Dixon, DA;Gutowski, M
通讯作者：
Gutowski, M
影响因子：
4
作者：
Ping Wang;X. Kang
通讯作者：
Ping Wang;X. Kang
影响因子：
6.2
作者：
A. Züttel;S. Rentsch;P. Fischer;P. Wenger;P. Sudan;P. Mauron;Ch. Emmenegger
通讯作者：
A. Züttel;S. Rentsch;P. Fischer;P. Wenger;P. Sudan;P. Mauron;Ch. Emmenegger