Synthesis of Organic Compounds by Direct Carbonylation Reactions Using Metal Carbonyls.
Synthesis of Organic Compounds by Direct Carbonylation Reactions Using Metal Carbonyls.
复制标题
DOI：
10.1021/cr60218a001
复制
发表时间：
1962-08
期刊：
影响因子：
62.1
通讯作者：
C. W. Bird
中科院分区：
文献类型：
--
作者：
C. W. Bird
尽管将水煤气转化为碳氢化合物的费托工艺 (181) 自 1925 年以来就已为人所知，但其对羰基金属原位形成的依赖性并未立即得到认识，并且将金属羰基化合物应用于有机合成的大部分开创性工作是由 W. Reppe 和他在 I. G. Farben 的同事在第二次世界大战期间完成的 (30, 142)。这项工作的主要成果之一是通过与合成气和钴催化剂反应将烯烃转化为同系醛或醇的“Oxo”工艺（58、122、168、190）。事实上，直到最近几年，金属羰基化合物的合成应用才引起了学术界而非工业化学家的关注。这种兴趣的觉醒很大程度上源于对有机金属化合物的兴趣的复兴，这种兴趣是由以二茂铁为代表的新键合概念引起的(42, 203)。本综述的目的是总结我们目前关于过渡金属羰基化合物在掺入一个或多个一氧化碳单元的有机化合物合成中的应用的知识。为了避免与其他评论重叠，除非与本主题密切相关，否则未包括对诸如金属羰基化合物的化学、其有机金属衍生物及其在聚合反应中的应用等相关主题的讨论。本文回顾的反应的各种分类模式都是可行的，但没有一种是突出的，因为许多反应可以通过使用一种以上的羰基金属来完成，并且通常情况下，一个反应可以产生多种产物。
Although the Fischer-Tropsch process (181) for the conversion of water gas into hydrocarbons has been known since 1925, its dependence on the in situ formation of metal carbonyls was not recognized immediately and most of the pioneering work in the application of metal carbonyls to organic synthesis was carried out by W. Reppe and his co-workers at I. G. Farben during the Second World War (30, 142). One of the main results of this work was the “Oxo” process for the conversion of olefins into the homologous aldehydes or alcohols by reaction with synthesis gas and a cobalt catalyst (58, 122, 168, 190).It is in fact only over the last few years that the synthetic applications of metal carbonylshave attracted the attention of academic rather than industrial chemists. Much of thisawakening interest seems to stem from the revival of interest in organo-metallic com-pounds engendered by new concepts of bonding as typified by ferrocene (42, 203). The object of this review is to summarize our pres-ent knowledge as regards the application of transition metal carbonyls in the synthesis of organic compounds in which one or more carbon monoxide units have be-come incorporated. In order to avoid overlap with other reviews, discussion of such related topics as the chemistry of metal carbonyls, their organo-metallic derivatives, and their use in polymerization reactions has not been included except where germane to the present topic. Various modes of classification of the reactions herein reviewed arc feasible, but none is pre-eminent as many reactions can be accomplished by the use of more than one metal carbonyl and, not infrequently, a reaction may give rise to a multitude of products.