Metal-dependent regioselective oxidative coupling of 5,10,15-triarylporphyrins with DDQ-Sc(OTf)3 and formation of an oxo-quinoidal porphyrin
Metal-dependent regioselective oxidative coupling of 5,10,15-triarylporphyrins with DDQ-Sc(OTf)3 and formation of an oxo-quinoidal porphyrin
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DOI：
10.1021/ol0344826
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发表时间：
2003-06-12
期刊：
影响因子：
5.2
通讯作者：
Osuka, A
中科院分区：
文献类型：
--
作者：
Kamo, M;Tsuda, A;Osuka, A
5，10，15-三芳基卟啉金属配合物与DDQ-Sc（OTf）（3）的氧化偶联反应的区域选择性取决于中心金属和meso-芳基取代基。在相同的条件下，由Ni（II）卟啉得到氧代醌式卟啉。
Regloselectivity of the oxidative coupling of 5,10,15-triarylporphyrin metal complexes with DDQ-Sc(OTf)(3) was dependent on the central metal and meso-aryl substituent. Oxo-quinoidal porphyrin was obtained from Ni(II) porphyrin under the same conditions.