Over 12% efficient low-bandgap CuIn(S, Se)(2) solar cells with the absorber processed from aqueous metal complexes solution in air
Over 12% efficient low-bandgap CuIn(S, Se)(2) solar cells with the absorber processed from aqueous metal complexes solution in air
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超过％2012％％20效率％20低带隙％20CuIn（S，％20Se）（2）％20太阳能％20细胞％20与％20％20吸收剂％20加工％20来自％20水％20金属％20复合物％20溶液％20in％20空气
DOI：
10.1016/j.nanoen.2019.06.010
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发表时间：
2019
期刊：
影响因子：
17.6
通讯作者：
Huang Wei
中科院分区：
文献类型：
--
作者：
Wu Sanping;Jiang Jingjing;Yu Shaotang;Gong Yuancai;Yan Weibo;Xin Hao;Huang Wei
从环境友好的溶液在环境空气中制造吸收体是解决限制黄铜矿太阳能电池商业化的成本和环境问题的理想方法。在这里，我们报告CuIn（S，Se）2（CISSe）太阳能电池的吸收剂从水溶液中使用金属硫脲配合物CuTU3Cl和InTU3Cl3作为前体制造。所有金属离子与络合物中硫的直接键合防止铟的水解并促进热退火时金属硫化物的形成。采用简单的水溶液在空气中制备了膜厚穿透大晶粒、表面光滑的高质量低带隙CISSe吸收材料。获得了功率转换效率为12.3%的CISSe太阳能电池。
Fabrication of the absorber from environmentally benign solution in ambient air is the ideal approach to address the cost and environmental issues that limit chalcopyrite solar cell commercialization. Here, we report CuIn(S,Se)2(CISSe) solar cells with the absorber fabricated from an aqueous solution using metal thiourea complexes CuTU3Cl and InTU3Cl3as precursors. The direct bonding of all metal ions with sulphur in the complexes prevents the hydrolysis of indium and promote the formation of metal sulphide upon thermal annealing. High quality low band gap CISSe absorber material with film thickness penetrating large grains and smooth surface is fabricated from the simple aqueous solution in air. CISSe solar cell with a power conversion efficiency of 12.3% is achieved.