Inkjet Printing of Conductive Silver Patterns by Using the First Aqueous Particle-Free MOD Ink without Additional Stabilizing Ligands
Inkjet Printing of Conductive Silver Patterns by Using the First Aqueous Particle-Free MOD Ink without Additional Stabilizing Ligands
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DOI：
10.1021/cm9036428
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发表时间：
2010-05-25
影响因子：
8.6
通讯作者：
Schmidt, Peer
中科院分区：
文献类型：
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作者：
Jahn, Stephan F.;Blaudeck, Thomas;Schmidt, Peer
讨论了[AgO2C(CH2OCH2)(3)H](3)的化学和物理性质及其作为压电喷墨印刷用无配体MOD油墨（MOD =金属有机分解）的应用。印刷、热敏或光化学烧结的银在玻璃(2.7 x 10（7) S m(-1)）和PET （PET =聚对苯二甲酸乙二醇酯）衬底(1.1 x 10（7) S m(-1)）上具有导电性，对应于体银导电性的43%和18%。胶带测试表明，这种油墨适用于特殊的聚合物基材。TG-MS研究表明，将3转化为元素银需要两步分解。用单x射线结构测定法测定了固态中3的结构。
The chemical and physical properties of [AgO2C(CH2OCH2)(3)H] (3) and its use as an aqueous, ligand-free MOD ink (MOD = metal - organic decomposition) for piezo inkjet printing is discussed. The printed, thermal, or photochemical sintered silver features are electrically conductive on glass (2.7 x 10(7) S m(-1)) and PET (PET = polyethylene terephthalate) substrates (1.1 x 10(7) S m(-1)) corresponding to 43% and 18% of the bulk silver conductivity. Conducted tape tests show the suitability of the ink for particularly polymer substrates. TG-MS studies demonstrate a two-step decomposition for the conversion of 3 to elemental silver. The structure of 3 in the solid state was determined by single X-ray structure determination.