A general method for the synthesis of nonracemic trans-epoxides: concise syntheses of trans-epoxide-containing insect sex pheromones.
A general method for the synthesis of nonracemic trans-epoxides: concise syntheses of trans-epoxide-containing insect sex pheromones.
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合成非外消旋反式环氧化物的通用方法：含反式环氧化物的昆虫性信息素的简明合成。
作者：
Baldip Kang;R. Britton
已经开发出一种合成手性非外消旋反式环氧化物的通用方法，该方法可以从醛快速获得烷基、烯基、炔基和苯基取代的反式环氧化物。该方法也已应用于含反式环氧化物的昆虫性信息素的简洁和高产合成。
A general method for the synthesis of chiral nonracemic trans-epoxides has been developed that provides rapid access to alkyl-, alkenyl-, alkynyl-, and phenyl-substituted trans-epoxides from aldehydes. This methodology has also been applied in concise and high-yielding syntheses of both trans-epoxide containing insect sex pheromones.