Synthesis of pyrrolidinium-based plastic crystals exhibiting high ionic conductivity at ambient temperature
Synthesis of pyrrolidinium-based plastic crystals exhibiting high ionic conductivity at ambient temperature
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室温下具有高离子电导率的吡咯烷鎓塑料晶体的合成
DOI：
10.1039/c8nj05127e
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发表时间：
2019
影响因子：
3.3
通讯作者：
Yoshizawa-Fujita Masahiro
中科院分区：
文献类型：
--
作者：
Yamaguchi Shun;Yamada Hiromasa;Takeoka Yuko;Rikukawa Masahiro;Yoshizawa-Fujita Masahiro
本文研究了吡咯烷基OIPC与不同阴离子组分的合成，探讨了阴离子结构对OIPC性能的影响。特别研究了离子电导率与阴离子和阳离子离子半径比（ρ）的关系。结果表明，ρ值较小的OIPCs具有较高的离子电导率。
In this work, pyrrolidinium-based OIPCs were synthesised together with various anionic species to investigate the effect of the anion structure on the OIPC properties. In particular, the relationship between the ionic conductivity and ionic radius ratio (ρ) of the anion and cation was investigated. The results suggested that OIPCs with a smaller ρ value were found to exhibit a higher ionic conductivity.