Organometallic- and organic-based magnets: New chemistry and new materials for the new millennium
Organometallic- and organic-based magnets: New chemistry and new materials for the new millennium
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DOI：
10.1021/ic000540x
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发表时间：
2000-09
影响因子：
4.6
通讯作者：
Joel S A Miller
中科院分区：
文献类型：
--
作者：
Joel S A Miller
有机物和有机基材料表现出技术上的重要性质的大块磁性的设计，制备和研究。这些磁体通过传统的有机化学方法制备，与传统的无机基磁体不同，不需要冶金加工。此外，这些磁体通常可溶于常规溶剂中，并且实例具有超过铁金属（基于Fe或摩尔）的饱和磁化强度。此外，已经制备了临界温度超过室温的磁体、矫顽场超过Co5Sm的磁体和薄膜磁体。本文重点介绍了我们以及亚瑟J.爱泼斯坦实验室的集体联合研究。
Organometallic- and organic-based materials exhibiting the technologically important property of bulk magnetism have been designed, prepared, and studied. These magnets are prepared via conventional organic chemistry methodologies and unlike conventional inorganic-based magnets do not require metallurgical processing. Furthermore, these magnets are frequently soluble in conventional solvents, and examples have saturation magnetizations exceeding that of iron metal on an Fe or mole basis. Also, magnets with critical temperatures exceeding room temperature, magnets with coercive fields exceeding that of Co5Sm, and thin-film magnets have been prepared. This article highlights the collective joint research executed in our, as well as Arthur J. Epstein's, laboratories.