High-Spin Organic Molecules
High-Spin Organic Molecules
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DOI：
10.1021/jo502505r
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发表时间：
2015-02-06
影响因子：
3.6
通讯作者：
Rajca, Andrzej
中科院分区：
文献类型：
--
作者：
Gallagher, Nolan M.;Olankitwanit, Arnon;Rajca, Andrzej
具有高自旋基态的有机分子除了具有基本的吸引力外，还在有机磁性、核磁共振造影剂和自旋电子学等领域具有潜在的应用前景。这类分子曾经被认为只作为高活性的中间体存在，但可以合理地设计成对有机合成和表征具有足够的稳定性。本文概述了导致高自旋基态的因素以及高自旋有机分子的设计和合成的最新进展。
Organic molecules with high-spin ground states, besides being fundamentally interesting, possess numerous potential applications in diverse fields such organic magnetism, MRI contrast agents, and spintronics. Such molecules, once thought to exist only as highly reactive intermediates, can be rationally designed to have adequate stability for organic synthesis and characterization. This Synopsis provides an overview of the factors that lead to high-spin ground states as well as recent progress in the design and synthesis of high-spin organic molecules.