Identification of a sex pheromone component of the geometrid moth Milionia basalis pryeri

Identification of a sex pheromone component of the geometrid moth Milionia basalis pryeri
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DOI:
10.1007/s10886-005-2052-3
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发表时间:
2005-03-01
影响因子:
2.3
通讯作者:
Ando, T
Ando, T
中科院分区:
环境科学与生态学2区
文献类型:
--
作者:
Yasui, H;Wakamura, S;Ando, T

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一个单一的成分在处女母Milionia basalis pryeri蛾提取物引起的反应,从配偶蛾触角。该化合物(CA。通过GC-MS和NMR分析、微量化学反应和比较手性HPLC,鉴定为(Z,Z)-(3S,4 R)-3,4-环氧十九碳-6,9-二烯。在田间试验中,合成的(Z,Z)-(3S,4 R)-3,4-环氧十九碳-6,9-二烯吸引雄蛾。相反的对映异构体、外消旋混合物和保持在小笼中的处女雌蛾比溶剂对照吸引的蛾不多。
A single component in extracts of virgin female Milionia basalis pryeri moths elicited responses from mate moth antennae. This compound (ca. 7 ng/female) was identified as (Z,Z)-(3S,4R)-3,4-epoxynonadeca-6,9-diene by GC-MS and NMR analyses, microchemical reactions, and comparative chiral HPLC. In a field test, synthetic (Z,Z)-(3S,4R)-3,4-epoxynonadeca-6,9-diene attracted male moths. The opposite enantiomer, the racemic mixture, and virgin female moths held in small cages attracted no more moths than the solvent controls.