Hydrogen Bonding in M (OD) 2 Compounds Under Pressure
Hydrogen Bonding in M (OD) 2 Compounds Under Pressure
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M (OD) 2 化合物在压力下的氢键作用
DOI:
10.4131/jshpreview.7.211
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发表时间:
1998
期刊:
影响因子:
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通讯作者:
S. Klotz
中科院分区:
文献类型:
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作者:
J. Parise;Hugh Cox;H. Kagi;Rui Li;W. G. Marshall;J. Loveday;S. Klotz
The structures of the deuterated hydroxides (M (OD) 2; M=Mg, Ca, Mn, Ni, Co) have been refined using the Rietveld method and neutron powder diffraction data collected at high pressure. There is no statistically significant increase in the O-D interatomic distance at increased pressure while the hydrogen bonding interaction D. . . O increases as this distance decreases and the O-D. . . O angle increases. The intramolecular O-D bond valences, determined indirectly from the intermolecular D. . . O distances, decrease steadily for all materials as pressure is increased.
DOI:
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发表时间:
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