Concise Formal Synthesis of (+)-Englerin A and Total Synthesis of (-)-Orientalol F: Establishment of the Stereochemistry of the Organocatalytic [4+3]-Cycloaddition Reaction
Concise Formal Synthesis of (+)-Englerin A and Total Synthesis of (-)-Orientalol F: Establishment of the Stereochemistry of the Organocatalytic [4+3]-Cycloaddition Reaction
复制标题
( )-Englerin A 的简洁形式合成和 (-)-Orientalol F 的全合成：有机催化[4 3]-环加成反应立体化学的建立
DOI：
10.1055/s-0031-1290090
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发表时间：
2012-01-01
期刊：
影响因子：
2
通讯作者：
Shang, Yong-Jia
中科院分区：
文献类型：
--
作者：
Wang, Chao-Lei;Sun, Bing-Feng;Shang, Yong-Jia
以三烯为原料，成功地完成了（+）-englerin A的对映选择性缩甲醛合成和（-）-orientalol F的全合成。这一成功使得有机催化[4+3]-环加成反应的相对和绝对立体化学得以建立。
The enantioselective formal synthesis of (+)-englerin A and the total synthesis of (-)-orientalol F were successfully accomplished via a triene. The success enabled establishment of the relative as well as absolute stereochemistry of the organocatalytic [4+3]-cycloaddition reaction.