Monocyclopentadienyl Halide Complexes of the d- and f-Block Elements
Monocyclopentadienyl Halide Complexes of the d- and f-Block Elements
复制标题
d-和f-嵌段元素的单环戊二烯基卤化物配合物
DOI：
10.1002/chin.199150264
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发表时间：
1991
期刊：
影响因子：
--
通讯作者：
R. Poli
中科院分区：
文献类型：
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作者：
R. Poli
在首次报道二茂铁之后不久，就制备了同时含有双金属和卤化物配体的配合物。从历史上看，第一批开发的系统是那些含有一个以上环戊二烯基环的系统。在威尔金森和科顿于1959年发表的关于环戊二烯基金属化合物的最早综述文章中，1仅报道了TiCp2X2、ZrCp2X2、VCp2X2、MCp2Br3（M=Nb、Ta）、MoCp2Cl2和UCp3Cl，尽管已经开发了用于低氧化态羰基衍生物的单环戊二烯基化学。到1964年，双Cp化合物的列表已经扩展到Hf和几种稀土MCp2Cl系统，而最初的几种单Cp系统开始出现，例如CpTiX3，CpTiCl2，CpZrCl3和CpCrX2。2.含有两个双环的体系的化学发展非常迅速，
Complexes containing both cyclopentadienyl and halide ligands were prepared soon after the first report of ferrocene. Historically, the first systems to be de-veloped were those containing more than one cyclo-pentadienyl ring. In the earliest review article on cy-clopentadienyl metal compounds by Wilkinson and Cotton in 1959, 1 only TiCp2X2, ZrCp2X2, VCp2X2, MCp2Br3 (M=Nb, Ta), MoCp2Cl2, and UCp3Cl were reported, although monocyclopentadienyl chemistry was already developed for low oxidation state carbonyl derivatives. By 1964, the list of bis-Cp compounds had been extended to Hf and several rare earth MCp2Cl systems, while the first few mono-Cp systems started to appear, eg CpTiX3, CpTiCl2, CpZrCl3, and CpCrX2. 2 The chemistry of systems containing two cyclopentadienyl rings developed very rapidly while studies