Sulfonium ion-promoted traceless Schmidt reaction of alkyl azides
Sulfonium ion-promoted traceless Schmidt reaction of alkyl azides
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DOI：
10.1039/d1cc02770k
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发表时间：
2021-08-03
影响因子：
4.9
通讯作者：
Kakiuchi, Kiyomi
中科院分区：
文献类型：
--
作者：
Ardiansah, Bayu;Tanimoto, Hiroki;Kakiuchi, Kiyomi
介绍了锍离子的施密特反应。一般的伯、仲和叔烷基叠氮化物被转化为相应的羰基或亚胺化合物，而没有任何痕量的活化剂。这种通过C-H和C-C键的1，2-迁移的断键反应可用于一锅取代反应。
Schmidt reaction by sulfonium ions is described. General primary, secondary, and tertiary alkyl azides were converted to the corresponding carbonyl or imine compounds without any trace of the activators. This bond scission reaction through 1,2-migration of C-H and C-C bonds was accessible to the one-pot substitution reaction.