Lupane-triterpene esters from the leaves of Ceriops decandra (Griff.) Ding Hou

Lupane-triterpene esters from the leaves of Ceriops decandra (Griff.) Ding Hou
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DOI:
10.1071/ch05087
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发表时间:
2005-01-01
影响因子:
1.1
通讯作者:
Thongdeeying, P
Thongdeeying, P
中科院分区:
化学4区
文献类型:
--
作者:
Ponglimanont, C;Thongdeeying, P

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除了16种已知的三萜之外,还从Ceriops decandra的叶中分离出两种新的三萜酯:羽扇豆酮3,羽扇豆醇4,桦木醛5,3 β-Z-香豆酰羽扇豆醇6,3 β-E-香豆酰羽扇豆醇7,3-表-桦木酸8,桦木醇9,桦木酸10,3 β-E-阿魏酰桦木醇11,30-去甲-卢普-3 β-醇-20-酮12,3 β-E-咖啡酰羽扇豆醇13,羽扇豆-20(29)-烯-3 β,30-二醇14,3 β-羟基羽扇豆-29-酸15,3 β,20-二羟基羽扇豆烷16,以及齐墩果酸和熊果酸的混合物17和18。通过光谱方法确定新化合物为3 β-E-阿魏酰羽扇豆醇1和3 β-Z-阿魏酰羽扇豆醇2。化合物3和5-16为首次报道的C. decandra
Two novel triterpene esters were isolated from the leaves of Ceriops decandra in addition to 16 known triterpenes: lupenone 3, lupeol 4, betulinaldehyde 5, 3 beta-Z-coumaroyllupeol 6, 3 beta-E-coumaroyllupeol 7, 3-epi-betulinic acid 8, betulin 9, betulinic acid 10, 3 beta-E-feruloylbetulin 11, 30-nor-lup-3 beta-ol-20-one 12, 3 beta-E-caffeoyllupeol 13, lup-20(29)-en-3 beta,30-diol 14, 3 beta-hydroxylupan-29-oic acid 15, 3 beta,20-dihydroxylupane 16, and a mixture of oleanolic and ursolic acid 17 and 18. The new compounds were determined by spectroscopic methods to be 3 beta-E-feruloyllupeol 1 and 3 beta-Z-feruloyllupeol 2. Compounds 3 and 5-16 were reported for the first time as metabolites of C. decandra.