Isolation and absolute configuration determination of aliphatic sulfates as the Daphnia kairomones inducing morphological defense of a phytoplankton-part 2.
Isolation and absolute configuration determination of aliphatic sulfates as the Daphnia kairomones inducing morphological defense of a phytoplankton-part 2.
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DOI：
10.1248/cpb.56.129
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发表时间：
2008
影响因子：
1.7
通讯作者：
Ko Yasumoto;Akinori Nishigami;Hiroaki Aoi;Chise Tsuchihashi;F. Kasai;T. Kusumi;T. Ooi
中科院分区：
文献类型：
--
作者：
Ko Yasumoto;Akinori Nishigami;Hiroaki Aoi;Chise Tsuchihashi;F. Kasai;T. Kusumi;T. Ooi
从水溞中分离出 4,8-二甲基壬基硫酸盐 (1) 和 3-甲基-4E-癸烯基硫酸盐 (2)，作为水蚤利他素诱导淡水浮游植物 Scenedesmus gutwinskii var. 的形态防御。异脊柱（NIES-802）。 1 的 C4 绝对构型通过适用于醇 3 的 Ohrui 方法测定。2 的 C3 绝对立体化学通过醇 11 的 (R)-1NMA 酯的 (1) H-NMR 分析测定。
4,8-Dimethylnonyl sulfate (1) and 3-methyl-4E-decenyl sulfate (2) were isolated from Daphnia pulex as the Daphnia kairomones that induced morphological defense of a freshwater phytoplankton Scenedesmus gutwinskii var. heterospina (NIES-802). The absolute configuration at C4 of 1 was determined by Ohrui's method applied to alcohol 3. The absolute stereochemistry at C3 of 2 was determined by (1)H-NMR analysis of the (R)-1NMA ester of alcohol 11.