Controlling the crystalline three-dimensional order in bulk materials by single-wall carbon nanotubes

Controlling the crystalline three-dimensional order in bulk materials by single-wall carbon nanotubes
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通过单壁碳纳米管控制块状材料的晶体三维有序

DOI:
10.1038/ncomms4763
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发表时间:
2014
影响因子:
16.6
通讯作者:
N. Martin
N. Martin
中科院分区:
综合性期刊1区
文献类型:
--
作者:
J. Lopez-Andarias;J.L. Lopez;C. Atienza;F.G. Brunetti;C. Romero-Nieto;D.M. Guldi;N. Martin

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在纳米尺度上构建有序单壁碳纳米管软材料是目前科学界的一个重要挑战。在这里,我们使用单壁碳纳米管作为工具来控制由适当功能化的分子构建块组成的三维块状材料的晶体有序性。我们用含有三肽和五肽的小分子制备p型纳米纤维,这些小分子共价连接到羧基和给电子9,10-二(1,3-二硫醇-2-亚基)-9,10-二氢蒽末端。将少量单壁碳纳米管添加到如此制备的纳米纤维中,并通过 Ca2+ 的电荷筛选进行外部控制的自组装,产生了新型稳定的基于单壁碳纳米管的超分子凝胶,其具有显着的长程内部有序性。
The construction of ordered single-wall carbon nanotube soft-materials at the nanoscale is currently an important challenge in science. Here we use single-wall carbon nanotubes as a tool to gain control over the crystalline ordering of three-dimensional bulk materials composed of suitably functionalized molecular building blocks. We preparep-type nanofibres from tripeptide and pentapeptide-containing small molecules, which are covalently connected to both carboxylic and electron-donating 9,10-di(1,3-dithiol-2-ylidene)-9,10-dihydroanthracene termini. Adding small amounts of single-wall carbon nanotubes to the so-preparedp-nanofibres together with the externally controlled self assembly by charge screening by means of Ca2+results in new and stable single-wall carbon nanotube-based supramolecular gels featuring remarkably long-range internal order.
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发表时间: 2008-07
期刊: Angewandte Chemie
影响因子: --
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