Chemiluminescence in molecular recognition: base-induced decomposition of optically active dioxetanes bearing a bisnaphthol moiety with a complex of optically active crown ether-potassium tert-butoxide.
Chemiluminescence in molecular recognition: base-induced decomposition of optically active dioxetanes bearing a bisnaphthol moiety with a complex of optically active crown ether-potassium tert-butoxide.
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DOI：
10.1039/b414001j
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发表时间：
2005-02
影响因子：
4.9
通讯作者：
M. Matsumoto;Koji Hamaoka;Yuji Takashima;Mizuki Yokokawa;Kazutaka Yamada;N. Watanabe;H. K. Ijuin
中科院分区：
文献类型：
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作者：
M. Matsumoto;Koji Hamaoka;Yuji Takashima;Mizuki Yokokawa;Kazutaka Yamada;N. Watanabe;H. K. Ijuin
通过光学活性冠醚与叔丁醇钾的络合物的作用，二氧杂环丁烷(1)的四种光学纯异构体分解，产生具有λ(max)CL的光，并给出四种不同的光谱形状。
Four optically pure isomers of dioxetane (1) were decomposed by the action of the complex of an optically active crown ether with potassium tert-butoxide to afford light with lambda(max)CL and gave four different spectrum shapes.