Electrical and thermal properties of titanium hydrides

Electrical and thermal properties of titanium hydrides
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DOI:
10.1016/j.jallcom.2005.10.032
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发表时间:
2006-08
影响因子:
6.2
通讯作者:
Masato Ito;D. Setoyama;J. Matsunaga;H. Muta;K. Kurosaki;M. Uno;S. Yamanaka
Masato Ito;D. Setoyama;J. Matsunaga;H. Muta;K. Kurosaki;M. Uno;S. Yamanaka
中科院分区:
材料科学2区
文献类型:
--
作者:
Masato Ito;D. Setoyama;J. Matsunaga;H. Muta;K. Kurosaki;M. Uno;S. Yamanaka

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制备了不同形状的无缺陷块状氢化钛(TiHX:X=1.53~1.75),并对其电学和热学性能进行了研究。氢化钛的电导率略低于金属钛,表现出类似金属的温度依赖性。由于氢化作用,Ti-H体系的塞贝克系数由正变负,氢化钛的塞贝克系数的绝对值保持在较低的水平,这是金属材料的典型特征。氢化物的导热系数与金属相同,但随温度升高略有增加。
Various shapes of flaw-free bulk titanium hydrides (TiHX: X=1.53–1.75) were fabricated, and its electrical and thermal properties were studied. The electrical conductivity of titanium hydride was slightly lower than that of titanium metal, and it exhibited metal-like temperature dependence. The Seebeck coefficient of the Ti–H system changed from positive to negative due to hydrogenation, and its absolute value for titanium hydride remained at a low magnitude, which is typical for metallic materials. The thermal conductivity of the hydride was the same as that of the metal and increased slightly with increasing temperature.