A Ni-Mg-Al layered triple hydroxide-supported Pd catalyst for heterogeneous acceptorless dehydrogenative aromatization

A Ni-Mg-Al layered triple hydroxide-supported Pd catalyst for heterogeneous acceptorless dehydrogenative aromatization
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DOI:
10.1039/c7cc01182b
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发表时间:
2017-05-11
影响因子:
4.9
通讯作者:
Mizuno, Noritaka
Mizuno, Noritaka
中科院分区:
化学2区
文献类型:
--
作者:
Jin, Xiongjie;Taniguchi, Kento;Mizuno, Noritaka

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在Ni-Mg-Al层状氢氧化物负载Pd催化剂存在下,随着分子氢的释放,多种环己醇/环己酮和环己胺的无受体脱氢芳构化反应有效地进行,分别得到相应的苯酚和苯胺。
In the presence of a Ni-Mg-Al layered triple hydroxide-supported Pd catalyst, the acceptorless dehydrogenative aromatization of a wide range of cyclohexanols/cyclohexanones and cyclohexylamines efficiently proceeded to give the corresponding phenols and anilines, respectively, inmoderate to high yields with the liberation of molecular hydrogen.