Hydrogen evolution from water with visible radiation in presence of Cu(II)/WO3 and electron relay

Hydrogen evolution from water with visible radiation in presence of Cu(II)/WO3 and electron relay
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DOI:
10.1016/0360-3199(89)90109-2
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发表时间:
1989
影响因子:
7.2
通讯作者:
P. Maruthamuthu;M. Ashokkumar;K. Gurunathan;E. Subramanian;M. Sastri
P. Maruthamuthu;M. Ashokkumar;K. Gurunathan;E. Subramanian;M. Sastri
中科院分区:
工程技术2区
文献类型:
--
作者:
P. Maruthamuthu;M. Ashokkumar;K. Gurunathan;E. Subramanian;M. Sastri

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Cu(II)掺杂的WO3粒子在甲基紫精和可见光辐射的存在下,发现从水中更有效地析出氢。甲基紫精被用作半导体导带电子转移到水溶液中存在的氢离子的电子中继。发现Cu(II)离子的摩尔百分比的增加会增加析氢速率。
Cu(II)-doped WO3particles in presence of methylviologen and visible radiation are found to evolve hydrogen from water more efficiently. Methylviologen has been used as an electron relay for the transfer of conduction band electron of the semiconductor to the hydrogen ion present in the aqueous solution. Increase in the molar percentage of Cu(II) ions is found to increase the hydrogen evolution rate.