Chemical reactivity of Sc3N@C80 and La2@C80
Chemical reactivity of Sc3N@C80 and La2@C80
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DOI：
10.1021/ja052534b
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发表时间：
2005-07-20
影响因子：
15
通讯作者：
Nagase, S
中科院分区：
文献类型：
--
作者：
Iiduka, Y;Ikenaga, O;Nagase, S
尽管Sc3N@C80具有与La2@C80相同的碳笼（Ih）和氧化态（C806-），但Sc3N@C80的热反应性比La2@C80低。这一结果归因于Sc3N@C80和La2@C80之间的能级和LUMO分布的差异。
Sc3N@C80has a lower thermal reactivity than La2@C80, although Sc3N@C80has the same carbon cage (Ih) and oxidation state (C806-) as La2@C80. This result is attributed to the difference in the energy level and distribution of LUMO between Sc3N@C80and La2@C80.