Micro-Chemical and Spectroscopic Study of Component Materials in 18th and 19th Century Sacred Books
Micro-Chemical and Spectroscopic Study of Component Materials in 18th and 19th Century Sacred Books
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18 世纪和 19 世纪圣书中成分材料的微化学和光谱研究
DOI：
10.1515/res-2016-0027
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发表时间：
2017
期刊：
影响因子：
--
通讯作者：
B. Minčeva
中科院分区：
文献类型：
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作者：
Maja Kostadinovska;O. Grupče;Zorica Jakovleska Spirovska;B. Minčeva
摘要 西里尔文书籍《五月的男性学》（1705 年）、《圣经》（1822 年）和《镜子》（1816 年）被托付给斯科普里国家图书馆的保护实验室进行保护。前两本书在莫斯科印刷，第三本书在维也纳发行，尽管它起源于前奥斯曼帝国，现在的马其顿共和国的领土。为了设计保护方案，对书中使用的纸张和墨水进行了表征并评估了它们的状况。使用微量化学测试来确定添加到纸浆中的纸纤维和材料的类型。应用 FTIR 来确认纸质载体中的施胶剂和填料的结果。通过显微拉曼光谱分析无机颜料。俄罗斯书籍中的原始纸张是由木质素含量低于 5% 的碎布制成的，而《镜子》中的纸张是由未漂白的原始硬木制成的。已经确定了不同类型的上浆：Menology for May 和 Mirror 中的明胶/明矾，以及 The Bible 中的明胶/松香。鉴定出的颜料为灯黑、朱红、普鲁士蓝和方解石。该研究阐明了哪些内部和外部因素可能导致书籍进一步腐烂，并将有助于就进一步保存这些物品做出明智的决定。
Abstract The Cyrillic books Menology for May (1705), The Bible (1822) and Mirror (1816) were consigned for conservation to the Conservation Laboratory at the National Library in Skopje. The first two books were printed in Moscow, while the third book was issued in Vienna, although it originates from the territory of the former Ottoman Empire, present-day Republic of Macedonia. In order to design a conservation protocol, papers and inks used in the books were characterized and their condition was assessed. Micro-chemical tests were used in order to identify the type of paper fibres and materials added to the paper pulp. FTIR was applied to confirm the findings for the sizing and fillers found in the paper support. Inorganic pigments were analysed by micro-Raman spectroscopy. The original paper in the Russian books was made of rags with less than 5 % lignin content present, whereas the paper in Mirror was made of raw and unbleached hardwood. Distinct types of sizing have been identified: gelatine/alum in Menology for May and Mirror and gelatine/rosin in The Bible. The pigments identified are lamp black, vermilion, Prussian blue and calcite. The study elucidates which internal and external factors could cause further decay of the books and will help in making informed decisions concerning the further preservation of the objects.