Exo-Selective and Enantioselective Photoenolization/Diels-Alder Reaction
Exo-Selective and Enantioselective Photoenolization/Diels-Alder Reaction
复制标题
外型选择性和对映选择性光烯醇化/Diels-Alder 反应
DOI：
10.1021/acs.orglett.1c02719
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发表时间：
2021-09-22
期刊：
影响因子：
5.2
通讯作者：
Gao, Shuanhu
中科院分区：
文献类型：
--
作者：
Hou, Min;Xu, Mengmeng;Gao, Shuanhu
An unusual exo-selective photoenolization/Diels-Alder reaction of electron-rich 2-methylbenzaldehydes and dienophiles containing a benzoyl group at its alpha position was reported herein. The chiral TADDOL-type ligand plays a key role in this process: (1) accelerating the reaction; (2) controlling the enantioselectivity; and (3) improving and tuning the diastereoselectivity of the reaction.
