Phosphorescent organic light-emitting devices: working principle and iridium based emitter materials.

Phosphorescent organic light-emitting devices: working principle and iridium based emitter materials.
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磷光有机发光设备:工作原理和基于虹膜的发射极材料。

DOI:
10.3390/ijms9081527
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发表时间:
2008-08
影响因子:
5.6
通讯作者:
List EJW
List EJW
中科院分区:
生物学2区
文献类型:
--
作者:
Kappaun S;Slugovc C;List EJW

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尽管有机发光器件(OLED)技术已经发展到现在是液晶显示器(lcd)的重要竞争对手,但要使该技术完全商业化,还需要进一步的科学努力,致力于OLED的设计、工程和制造。沿着这些思路,本工作回顾了OLED技术的要点,特别关注单层和多层OLED的一般工作原理,荧光和磷光发射器材料以及掺杂磷光染料的宿主材料的转移过程。此外,作为磷光发射器材料的一个典型例子,本文简要讨论了同色和异色铱(III)配合物的合成、光物理性质和实现铱基磷光聚合物的方法。
Even though organic light-emitting device (OLED) technology has evolved to a point where it is now an important competitor to liquid crystal displays (LCDs), further scientific efforts devoted to the design, engineering and fabrication of OLEDs are required for complete commercialization of this technology. Along these lines, the present work reviews the essentials of OLED technology putting special focus on the general working principle of single and multilayer OLEDs, fluorescent and phosphorescent emitter materials as well as transfer processes in host materials doped with phosphorescent dyes. Moreover, as a prototypical example of phosphorescent emitter materials, a brief discussion of homo- and heteroleptic iridium(III) complexes is enclosed concentrating on their synthesis, photophysical properties and approaches for realizing iridium based phosphorescent polymers.
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