PHOTOLYSIS OF [n.2.2]PROPELLANONES INVOLVING A CYCLOBUTANONE RING
PHOTOLYSIS OF [n.2.2]PROPELLANONES INVOLVING A CYCLOBUTANONE RING
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涉及环丁酮环的[n.2.2]丙螺酮的光解作用
DOI：
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发表时间：
1982
期刊：
影响因子：
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通讯作者：
Y. Odaira
中科院分区：
文献类型：
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作者：
Y. Tobe;Y. Kanazawa;K. Kakiuchi;Y. Odaira
含有环丁酮环的[n.2.2]推进剂酮(5)和(6)在甲醇中的光解作用使环消除产物7和9高产出，特别是在高度应变的[3.2.2]推进剂酮(6)的情况下，通过α-裂解导致不利的酰基-烷基自由基对。
Photolysis of [n.2.2]propellanones (5) and (6) involving a cyclobutanone ring in methanol afforded the cycloelimination products 7 and 9 in good yields, especially in the case of highly strained [3.2.2]propellanone (6), via α-cleavage in the direction leading to the less favorable acyl-alkyl radical pair.