thermodynamic properties of liquid Ag-Si alloys
thermodynamic properties of liquid Ag-Si alloys
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液态银硅合金的热力学性能
DOI：
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发表时间：
1974
期刊：
影响因子：
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通讯作者：
J. Elliott
中科院分区：
文献类型：
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作者：
H. Sakao;J. Elliott
用硅饱和硅酸锂作电解质的电化学槽测量了液态Ag-Si合金中硅在1100 ~ 1325°C范围内的热力学性质。研究的组成范围为0.015 <xSi < 0.29。对于标准状态从纯液态硅到无限稀释硅的变化，其组成以原子分数计为：Si（I）= Si（inf. dil.）：△G° = 5，000 + 5.47T，（J/g-atom）研究结果与Hager在相图上的测量结果符合得很好。
The thermodynamic properties of silicon in liquid Ag-Si alloys in the range of 1100 to 1325°C have been measured by an electrochemical cell employing silica-saturated lithium silicate as the electrolyte. The range of composition studied is 0.015 <xSi < 0.29. For the change in standard state from pure liquid silicon to silicon at infinite dilution with the composition in atom fraction: Si(I) = Si (inf. dil.): △G° = 5,000 + 5.47T, (J/g-atom) The results of the study are in good agreement with the measurements on the phase diagram by Hager.