Electrically Conductive Gels Prepared from Syndiotactic Polystyrene and an Ionic Liquid

Electrically Conductive Gels Prepared from Syndiotactic Polystyrene and an Ionic Liquid
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由间规聚苯乙烯和离子液体制备的导电凝胶

DOI:
10.1021/acsomega.9b02310
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发表时间:
2019
期刊:
影响因子:
4.1
通讯作者:
Kuroki Masakatsu
Kuroki Masakatsu
中科院分区:
化学3区
文献类型:
--
作者:
Itagaki Hideyuki;Yoshida Naoto;Sano Takumi;Yokoyama Mayu;Iba Nozomi;Sugiyama Ryotaro;Kuroki Masakatsu

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系统地制备了含有大量离子液体溴化1-丁基吡啶([C4 py]Br)的间规聚苯乙烯(SPS)物理凝胶,并对其物理性质进行了详细的研究。该凝胶具有长时间的稳定形式,具有正常凝胶的储能弹性模量值。它们的电导率(~ 17 mS/cm)与[C4 py]Br的混合溶液的电导率几乎相同,表明[C4 py]Br在这些凝胶中的分布是均匀的,并且这些SPS凝胶中的电荷传输没有被由SPS δ晶相组成的SPS纤维的三维网络所中断。
Syndiotactic polystyrene (SPS) physical gels containing a large amount of the ionic liquid 1-butylpyridinium bromide ([C4py]Br) were systematically prepared and their physical properties were examined in detail. The gels had stable forms for a long time, having storage elastic modulus values of normal gels. They showed nearly the same values of the electrical conductivity (∼7 mS/cm) as those of the mixed solutions of [C4py]Br, suggesting that the distribution of [C4py]Br was uniform in these gels and that the charge transportation in these SPS gels was not interrupted by a three-dimensional network of SPS fibrils consisting of the SPS δ crystalline phases.
离子液体的物化:离子液体的聚合物电解质
DOI: --
发表时间: 2013
期刊:
影响因子: --
作者:
松尾二郎;草刈将一;藤井麻樹子;青木学聡;瀬木利夫;M. Watanabe
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溶剂类型对热可逆全同立构聚苯乙烯凝胶压缩模量浓度依赖性的影响
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期刊: Journal of Polymer Science Part B
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