Improved electrochemical properties by lithium insertion into Co3O4 in aqueous LiOH solution

Improved electrochemical properties by lithium insertion into Co3O4 in aqueous LiOH solution
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通过将锂嵌入到 LiOH 水溶液中的 Co3O4 中来改善电化学性能

DOI:
10.1016/j.pnsc.2013.11.010
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发表时间:
2013-12
期刊:
Progress in Natural Science:Materials International
影响因子:
--
通讯作者:
Ying Wu
Ying Wu
中科院分区:
其他
文献类型:
--
作者:
Yan Liu;Chengkang Chang;Dongyun Zhang;Ying Wu

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采用简单水热法合成了co3o4微球。第一次循环充放电试验在−0.6和0.6 Vvs之间进行。南加州爱迪生公司。用x射线衍射和扫描电镜对原始、放电和充电样品进行了表征。研究了不同浓度co3o4在LiOH溶液中的循环伏安曲线。两对氧化还原峰的出现表明,co3o4对licoo2和LiHCoO2的氧化还原反应涉及两组法拉第反应。
Co3O4microspheres were synthesized by a simple hydrothermal treatment. The first-cycle charge–discharge tests were carried out between −0.6 and 0.6 Vvs. SCE. The pristine, discharged and recharged specimens were characterized by X-ray power diffraction and scanning electron microscopy. Cyclic voltammetry (CV) curves of Co3O4at various concentrations in LiOH solution were investigated. The appearance of the two pairs of redox peaks indicated that two sets of faradaic reactions were involved in the redox reactions of Co3O4to LiCoO2and LiHCoO2.
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