Copper-Catalyzed Trifluoromethylation of Aryl and Vinyl Boronic Acids with An Electrophilic Trifluoromethylating Reagent
Copper-Catalyzed Trifluoromethylation of Aryl and Vinyl Boronic Acids with An Electrophilic Trifluoromethylating Reagent
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DOI：
10.1021/ol2005903
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发表时间：
2011-05-06
期刊：
影响因子：
5.2
通讯作者：
Shen, Qilong
中科院分区：
文献类型：
--
作者：
Liu, Tianfei;Shen, Qilong
描述了使用 Togni 试剂进行铜催化的芳基硼酸和烯基硼酸的三氟甲基化。对于一系列不同的底物（包括杂芳基硼酸和具有多种官能团的底物），该反应在温和的反应条件下以良好至优异的产率进行。
A copper-catalyzed trifluoromethylation of aryl- and alkenylboronic acids with Togni's reagent was described. The reaction proceeded in good to excellent yields for a range of different substrates including heteroarylboronic acids and substrates with a variety of functional groups under mild reaction conditions.