Molecular and crystal structures of tetra(methylgermanium) hexasulphide
Molecular and crystal structures of tetra(methylgermanium) hexasulphide
复制标题
六硫化四(甲基锗)的分子和晶体结构
DOI：
10.1039/dt9730000543
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发表时间：
1973
期刊：
影响因子：
--
通讯作者：
C. J. Fritchie
中科院分区：
文献类型：
--
作者：
R. Benno;C. J. Fritchie
The title compound has been shown by X-ray crystallographic methods to have an adamantane-type structure. Mean distances and angles are Ge–S 2·218(3), Ge–C 1·922(10)A, S–Ge–S 111·8(3), Ge–S–Ge 104·6(2), and S–Ge–C 107·0(3)°. Crystals are monoclinic, space group C2/c, with a= 9·422(5), b= 16·779(8), c= 10·708(5)A, β= 107·94(3)°, and Z= 4. Molecular symmetry C2 is required. Refinement of 738 independent counter measured reflections gave R 5·2%.
