Hexacoordinate silicon species: a possible model for reaction intermediates. II: Nondissociative permutational isomerization in solution
Hexacoordinate silicon species: a possible model for reaction intermediates. II: Nondissociative permutational isomerization in solution
复制标题
六配位硅物种：反应中间体的可能模型。
DOI：
10.1021/om00109a047
复制
发表时间：
1989
期刊：
影响因子：
2.8
通讯作者：
Joachim. Zwecker
中科院分区：
文献类型：
--
作者：
C. Breliere;R. Corriu;G. Royo;Joachim. Zwecker
对具有螯合氮供体的分子内六配位硅化合物的研究表明，每种化合物都存在一对处于流动平衡的对映体。NMR特征与在没有键断裂的情况下发生的异构化机制一致。
Studies of intramolecularly hexacoordinated silicon compounds with chelating nitrogen donors have shown for each compound the existence of a pair of enantiomers in fluxional equilibrium. The NMR features are consistent with an isomerization mechanism that occurs without bond cleavage.