Codendronized Polymers: Wormlike Molecular Objects with a Segmented Structure
Codendronized Polymers: Wormlike Molecular Objects with a Segmented Structure
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共树枝聚合物：具有分段结构的蠕虫状分子物体
作者：
在此，我们报告了一系列新的codendronized聚合物与交替的嵌段结构制备的马来酰亚胺侧基与聚酯树枝和苯乙烯侧基与Percec型聚醚树枝的直接自由基共聚。这些树枝化聚合物具有不同的树枝化分子，具有相当高的摩尔质量，通过GPC测定与光散射检测器在温和的条件下获得。这些新的聚合物也已通过1H NMR，13 C NMR光谱，原子力显微镜（AFM），和小角X-射线散射（SAXS）进行了表征。所有的codendronized聚合物被证实持有交替结构，因此，它们具有分段结构。小角X射线散射结果表明，这些聚合物堆积在本体的六边形，并具有自组织结构的结构中结构的材料已获得其性能可以通过树枝化生成的调节。通过对其中一个侧基的进一步修饰，得到了两亲性的侧基化聚合物。这些...
Herein, we report a series of novel codendronized polymers with an alternating segmented structure prepared by direct radical copolymerization of maleimide pendent with polyester dendron and styrene pendent with Percec-type polyether dendron. These dendronized polymers bearing different dendrons with rather high molar masses as determined by GPC with light scattering detectors were obtained under mild conditions. These novel polymers have been also characterized by 1H NMR, 13C NMR spectroscopy, atomic force microscopy (AFM), and small-angle X-ray scattering (SAXS). All of the codendronized polymers were confirmed to hold an alternating structure; therefore, they have a segmented structure. The SAXS results indicate that these polymers pack hexagonally in bulk, and the materials with self-organized structures-in-structures have been thus obtained whose properties can be tuned by dendron generation. Through further modification of one pendent dendron, amphiphilic codendronized polymers were produced. These ...