Simultaneous tracking of sulfur species in the oxidation of thiourea by hydrogen peroxide.

Simultaneous tracking of sulfur species in the oxidation of thiourea by hydrogen peroxide.
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DOI：
10.1021/jp8003932
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发表时间：
2008-06
期刊：
The journal of physical chemistry. A
影响因子：
--
通讯作者：
Q. Gao;Guangping Wang;Yanyan Sun;I. Epstein
Q. Gao;Guangping Wang;Yanyan Sun;I. Epstein
中科院分区：
其他
文献类型：
--
作者：
Q. Gao;Guangping Wang;Yanyan Sun;I. Epstein

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We employ reversed-phase ion-pair high-performance liquid chromatography to quantitatively characterize the oxidation kinetics of thiourea oxidation by hydrogen peroxide. The HPLC technique makes it possible to monitor the concentrations of a variety of sulfur-containing species with different oxidation states and to elucidate the relative phase relations among them. The experimental results are in good agreement with simulations from an 8-step reaction mechanism.