Selective Formation and Optical Property of a 21-Helical Columnar Fluorophore Composed of Achiral 2-Anthracenecarboxylic Acid and Benzylamine
Selective Formation and Optical Property of a 21-Helical Columnar Fluorophore Composed of Achiral 2-Anthracenecarboxylic Acid and Benzylamine
复制标题
非手性2-蒽甲酸和苄胺组成的21螺旋柱状荧光团的选择性形成及其光学性质
DOI：
10.1021/cg800335t
复制
发表时间：
2008
影响因子：
3.8
通讯作者：
Y. Matsubara
中科院分区：
文献类型：
--
作者：
Y. Imai;Katuzo Murata;N. Asano;Y. Nakano;K. Kawaguchi;Takunori Harada;Tomohiro Sato;M. Fujiki;R. Kuroda;Y. Matsubara
将非手性荧光2-蒽甲酸与非手性苯甲胺反应，制得了具有圆偏振发光的手性21螺旋柱状有机荧光团。虽然该体系表现出多态，但通过改变结晶方法可以控制多态。
By using achiral fluorescent 2-anthracenecarboxylic acid with achiral benzylamine, a chiral 21-helical columnar organic fluorophore having circularly polarized luminescence (CPL) in the solid state is created. Although this system exhibits polymorphism, the polymorphism can be controlled by changing the crystallization method.