Ruthenium(II)-Catalyzed Decarboxylative C-H Activation: Versatile Routes to meta-Alkenylated Arenes
Ruthenium(II)-Catalyzed Decarboxylative C-H Activation: Versatile Routes to meta-Alkenylated Arenes
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DOI：
10.1002/anie.201600490
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发表时间：
2016-06-06
影响因子：
16.6
通讯作者：
Ackermann, Lutz
中科院分区：
文献类型：
--
作者：
Kumar, N. Y. Phani;Bechtoldt, Alexander;Ackermann, Lutz
钌（II）双（羧酸盐）的证明是非常有效的两个脱羧C-H烯基化策略。脱羧反应在相当低的温度下有效地进行。脱羧钌（II）催化剂的独特多功能性反映在与烯烃的氧化烯化以及炔的氧化还原中性氢芳基化中。
Ruthenium(II) bis(carboxylate)s proved highly effective for two decarboxylative C-H alkenylation strategies. The decarboxylation proceeded efficiently at rather low temperatures. The unique versatility of the decarboxylative ruthenium(II) catalysis is reflected in the oxidative olefinations with alkenes as well as the redox-neutral hydroarylations of alkynes.