Template polymerization of columnar architectures based on the salts of a carboxylic acid and 2-amino alcohols: application to the molecular recognition of 2-amino alcohols

Template polymerization of columnar architectures based on the salts of a carboxylic acid and 2-amino alcohols: application to the molecular recognition of 2-amino alcohols
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DOI:
10.1039/b305625b
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发表时间:
2003-09-21
影响因子:
4.9
通讯作者:
Saigo, K
Saigo, K
中科院分区:
化学2区
文献类型:
--
作者:
Ishida, Y;Amano, S;Saigo, K

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三烷氧基苯甲酸和2-氨基醇的盐显示出柱状液晶相;在可聚合的酸和去甲麻黄碱的盐的情况下,光聚合有效地在液晶状态下进行,并且所得固体吸附的2-氨基醇的大小,区域和对映选择性。
The salts of trialkoxybenzoic acids and 2-amino alcohols showed a columnar liquid crystalline phase; in the case of the salt of a polymerizable acid and norephedrine, the photo-polymerization proceeded efficiently in the liquid crystalline state, and the resultant solid adsorbed 2-amino alcohols size, regio-, and enantio-selectively.